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Boulders of the assemblage rubysapphire corundum, chromianmuscovite, margarite, tourmaline (chromian chlorite, ZnMnchromite and MnTi magnetite) occur in glacial moraineand rivers of north Westland, South Island of New Zealand. Thelocation, Cr-rich composition of the boulders and the presenceof rare serpentinite rinds indicate that they are derived fromultramafic rocks (Pounamu Ultramafics) that occur within AlpineSchist of the Southern Alps. The largest sample is progressivelyzoned outwards from a corundummargarite core, throughan intermediate zone of Cr-muscovite, to an outer zone of Cr-chloritethat is in contact with serpentinite. Most finds consist oferosion-resistant corundum-rich cores. In the corundum, Cr2O3content ranges from 0.5 to 13%, with red coloration becomingmore intense with increasing Cr. In addition to the dominantCr3+ Al3+ substitution, those of (Fe, V)3+ Cr3+ and (Ti4++Fe2+) 2Cr3+ result in spectacular colour zoning from colourlessto deep ruby red-carmine and pale blue to dark blueviolet.Corundum has grown by replacement of the micaceous matrix thatconsists of chromian muscovite (0.104.10% Cr2O3) andchromian margarite (0.461.20% Cr2O3). Both micas containa significant paragonite component (up to 21.5% in muscoviteand up to 40.8% in margarite). Late phase muscovite is Ba richwith up to 4.77% BaO, and margarite has up to 0.66% SrO. Tourmalineoccurs as veins, vein outgrowths and larger poikilitic crystalsthat replace the mica matrix. Chromium content ranges between0.82 and 3.6% Cr2O3. High bulk rock Al (up to 78% Al2O3), K,Ca, Cr and Na, and low Si (14.523.1% SiO2), suggest thatthe corundumCr-silicate rocks are the products of extrememetasomatic alteration of quartzofeldspathic schist enclavesin serpentinite. Isocon analysis indicates that conversion ofthe schist to the micaceous matrix of the corundum rocks involvesconservation of Ca, Al, K, volatiles and Sr, a mass loss of59% and a volume reduction of 69% consequent on removal of 7080%Si and all other elements (most >80%), with enrichment ofbetween 900 and 1800% Cr. The formation of corundum from themica matrix involved a further massvolume reduction anddecrements in Si, Ca, K, volatiles and Sr from reaction sites.Concentric mineral zonation in single rock samples and zoningreplacementin minerals, e.g. Cr in corundum and chromite, Ti, Fe2+ in corundum,Ba in muscovite, Sr in margarite, and Mn and Zn in chromiteand magnetite, imply element redistribution during metasomatism.Experimental reaction between quartzofeldspathic schist andserpentinite at 450C and 2 kbar produced reaction sequencescontaining newly formed Ca-plagioclasephlogopitic micachloriteand muscovitechlorite that in terms of composition areanalogous with the observed (corundummargarite)muscovitechloritezonation. The temperature of metamorphism of garnet zone rocks(45020C) that contain the corundumCr-silicate rocksis well below that of the breakdown of muscovite and margariteto form corundum and indicates the importance of fluid composition,particularly the cationhydrogen variables aCa2+/H+, aK+/H+and aS1O2. Introduction of boron into the schist (from serpentinite),and boron released from the breakdown of original tourmalinein the schist, resulted in tourmaline veining and reaction ofthe mica matrix to form tourmaline that invoved both a massand volume increase and addition of Fe, Mg together with B. KEY WORDS: corundumCr-silicate rocks; metasomatism; New Zealand; Southern Alps
*Corresponding author. 相似文献
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DERECKE PALMER 《Geophysical Prospecting》1991,39(8):1031-1060
The depth to the surface of a refractor and the seismic velocity within the refractor are very often intimately related. In the shallow environment, increased thicknesses of weathering occur in areas of jointing, shearing or lithological variations, and these zones of deeper weathering can have lower subweathering refractor velocities. This association is important in geotechnical investigations and in the measurement of weathering thicknesses and sub-weathering velocities for statics corrections for reflection seismic surveys. Algorithms, which employ forward and reverse traveltime data and which explicitly accommodate the offset distance through the process known as refraction migration, are necessary if detailed structure on a refractor and rapid lateral variations of the seismic velocity within it are to be resolved. These requirements are satisfied with wavefront construction techniques, Hales’ method and the generalized reciprocal method (GRM). However, these methods employ refraction migration in fundamentally different manners. Most methods compute an offset distance with an often imprecise knowledge of the seismic velocities of the overlying layers. In contrast, the GRM uses a range of offset distances from less than to greater than the optimum value, with the optimum value being selected with a minimum-variance criterion. The approach of the GRM is essential where there are undetected layers and where there are rapid variations in the depth to a refractor and the seismic velocity within it. In the latter situations the offset distance necessary to define the seismic velocities can differ considerably from the value required to define depths. The efficacy of the GRM in resolving structure and seismic velocity is demonstrated with three model studies and two field examples. 相似文献
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Kenneth PALMER Paul C. KENNEDY Barry ROSER 《Geostandards and Geoanalytical Research》1983,7(2):301-303
The concentrations of 20 trace elements in 6 British Chemical Standards (BCS) reference materials and 5 European Federation of Refractories Producers (PRE) reference materials have been determined by X-ray fluorescence spectrometry. 相似文献
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ABSTRACT. Recent attempts by U.S. politicians to reform the nation'sschools have shifted the goal of education to school accountability as assessed in standardized testing. Such an emphasis undermines geographical education in schools because of geography'ssuperficial representation in tests and in the social studies curriculum. Fieldwork done in the classroom can point to means of circumventing this dilemma. Collaborative fieldwork between college faculty members and public‐school teachers has the potential for adding geography to the social studies curriculum in a substantive way. Work conducted jointly by Hartwick College and the Oneonta (New York) Middle School exemplifies such a partnership. 相似文献
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The effectiveness of 2 methods for targeting observations is examined using a T21 L3 QG model in a perfect model context. Target gridpoints are chosen using the pseudo‐inverse (the inverse composed of the first three singular vectors only) and the quasi‐inverse or backward integration (running the tangent equations with a negative time‐step). The effectiveness of a target is measured by setting the analysis error to zero in a region surrounding the target and noting the impact on the forecast error in the verification region. In a post‐time setting, when the targets are based on forecast errors that are known exactly, both methods provide targets that are significantly better than targets chosen at random within a broad region upstream of the verification region. When uncertainty is added to the verifying analysis such that the forecast error is known inexactly, the pseudo‐inverse targets still perform very well, while the backward integration targets are degraded. This degradation due to forecast uncertainty is especially significant when the targets are a function of height as well as horizontal position. When an ensemble‐forecast difference is used in place of the inexact forecast error, the backward integration targets may be improved considerably. However, this significant improvement depends on the characteristics of the initial‐time ensemble perturbation. Pseudo‐inverse targets based on ensemble forecast differences are comparable to pseudo‐inverse targets based on exact forecast errors. Targets based on the largest analysis error are also found to be considerably more effective than random targets. The collocation of the backward integration and pseudo‐inverse targets appears to be a good indicator of target skill. 相似文献
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